Well, by default there is no such feature available in wordpress to delete his/her own account.
Even if you assign administrator privilege to user, he can modify aother users but cannot delete his/her own account.
While looking into WP arena, I have found one Plugin on wordpress i.e User Self Delete which will meet your requirement.
You can download and view more details on plugin at www[Dot]wordpress.org/extend/plugins/user-self-delete/
But in this plugin I did not found any option to send notification to administrator once user is deleted.
You can search google for similar plugin or modify the one I have provided you as per your requirement with the help of your web developer.
Last edited by WHUK-Brent; 10-08-10 at 07:27 AM.
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